Diels–Alder reactions of 1-phosphabutadienes: a highly selective route to PC-substituted phosphacyclohexenes-Reference-Cited by-同舟云学术

Diels–Alder reactions of 1-phosphabutadienes: a highly selective route to PC-substituted phosphacyclohexenes

Published:2020 Issue:5 Volume:56 Page:774-777
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ohtsuki Kazuaki¹²³⁴,Walsgrove Henry T. G.⁵⁶⁷⁸,Hayashi Yoshihiro¹²³⁴^ORCID,Kawauchi Susumu¹²³⁴,Patrick Brian O.⁵⁶⁷⁸,Gates Derek P.⁵⁶⁷⁸^ORCID,Ito Shigekazu¹²³⁴^ORCID

Affiliation:

1. School of Materials and Chemical Technology

2. Tokyo Institute of Technology

3. Meguro

4. Japan

5. Department of Chemistry

6. University of British Columbia

7. Vancouver

8. Canada

Abstract

Kinetically stabilized 1-phosphahaloprenes (2-halo-1-phosphabutadienes) as well as 1-phosphaisoprene undergo a hitherto unknown phospha-Diels–Alder dimerization of the PC–CC units upon heating.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Core Research for Evolutional Science and Technology

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC08997G

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