Formation of an Ag→Al dative bond is avoided in reactions of an alane/tris(phosphine) ligand with monovalent silver-Reference-Cited by-同舟云学术

Formation of an Ag→Al dative bond is avoided in reactions of an alane/tris(phosphine) ligand with monovalent silver

Published:2021 Issue:17 Volume:50 Page:5776-5778
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lai Qingheng¹²³⁴,Bhuvanesh Nattamai¹²³⁴,Zhou Jia⁵⁶⁷⁸,Ozerov Oleg V.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Texas A&M University

3. College Station

4. USA

5. State Key Laboratory of Urban Water Resource and Environment

6. Harbin Institute of Technology

7. Harbin 150090

8. China

Abstract

An alane/tris(phospine) ligand reacts with AgOTf and with Ag[HCB₁₁Cl₁₁] without establishing a dative Ag–Al bond. The Lewis-acidic Al instead binds to a triflate or to a phosphine.

Funder

National Science Foundation

State Key Laboratory of Urban Water Resource and Environment

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01068A

Reference29 articles.

1. σ-Acceptor, Z-type ligands for transition metals

2. Tunable σ-Accepting, Z-Type Ligands for Organometallic Catalysis

3. Coordination- and Redox-Noninnocent Behavior of Ambiphilic Ligands Containing Antimony

4. A d10Ni-(H2) Adduct as an Intermediate in HH Oxidative Addition across a NiB Bond

5. A Bimetallic Nickel–Gallium Complex Catalyzes CO2 Hydrogenation via the Intermediacy of an Anionic d10 Nickel Hydride

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Varied coordination geometries of an Alane/Tris(phosphine) ligand from its Reactions with Pt(0) and Au(I);Polyhedron;2024-11

2. Synthesis of pyrrole-based PSiP pincer ligands and their palladium, rhodium, and platinum complexes;Dalton Transactions;2022

3. Coordination chemistry and structural rearrangements of the Me₂PCH₂AlMe₂ ambiphilic ligand;Dalton Transactions;2022