Coordination chemistry and structural rearrangements of the Me2PCH2AlMe2 ambiphilic ligand-Reference-Cited by-同舟云学术

Coordination chemistry and structural rearrangements of the Me₂PCH₂AlMe₂ ambiphilic ligand

Published:2022 Issue:39 Volume:51 Page:15040-15048
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Paskaruk Katarina¹,Emslie David J. H.¹^ORCID,Britten James F.¹

Affiliation:

1. Department of Chemistry, McMaster University, 1280 Main Street West, Hamilton, Ontario, L8S 4M1, Canada

Abstract

Reactions between (Me2PCH2AlMe2)2 and late transition metal complexes led to five distinct outcomes, ranging from Me2PCH2AlMe2 coordination to in situ generation of a tris(phosphino)aluminate ligand.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02519A

Reference60 articles.

1. K. M.Paskaruk , B. E.Cowie and D. J. H.Emslie , in Comprehensive Coordination Chemistry III , ed. E. C. Constable , G. Parkin and L. Que Jr. , Elsevier , 2021 , vol. 1 , p. 717

2. Complexes of ambiphilic ligands: reactivity and catalytic applications

3. Reactions of Phosphine-Boranes and Related Frustrated Lewis Pairs with Transition Metal Complexes

4. Recent Developments in the Coordination Chemistry of Multidentate Ligands Featuring a Boron Moiety

5. Metal-Only Lewis Pairs with Transition Metal Lewis Bases

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