Fusing triphenylphosphine with tetraphenylborate: introducing the 9-phosphatriptycene-10-phenylborate (PTB) anion-Reference-Cited by-同舟云学术

Fusing triphenylphosphine with tetraphenylborate: introducing the 9-phosphatriptycene-10-phenylborate (PTB) anion

Published:2018 Issue:57 Volume:54 Page:7916-7919
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Drover Marcus W.¹²³⁴⁵^ORCID,Nagata Koichi¹²³⁴⁵,Peters Jonas C.¹²³⁴⁵^ORCID

Affiliation:

1. Division of Chemistry and Chemical Engineering

2. California Institute of Technology

3. Pasadena

4. California

5. USA

Abstract

In a fusion of two ubiquitous organometallic reagents, triphenylphosphine (PPh₃) and tetraphenylborate (BPh₄⁻), the 9-phosphatriptycene-10-phenylborate (PTB) anion has been prepared for the first time.

Funder

Japan Society for the Promotion of Science

Foundation for the National Institutes of Health

Natural Sciences and Engineering Research Council of Canada

Resnick Sustainability Institute for Science, Energy and Sustainability, California Institute of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC04321C

Reference35 articles.

1. Zwitterionic Relatives of Cationic Platinum Group Metal Complexes: Applications in Stoichiometric and Catalytic σ-Bond Activation

2. Zwitterionic Organometallates

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4. .pi.-Bonded complexes of the tetraphenylborate ion with rhodium(I) and iridium(I)

5. New homogeneous rhodium catalysts for the regioselective hydroboration of alkenes

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