P–S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica/IUQOEM
2. Universidad de Oviedo
3. E-33071 Oviedo
4. Spain
Abstract
P–S bond cleavage occurs in the title reactions to give arylphosphinidene complexes which may not bear a sulphido ligand.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT01450F
Reference66 articles.
1. K. B. Dillon , F.Mathey and J. F.Nixon, Phosphorus: The Carbon Copy, Wiley, New York, 1998
2. Multiple Bonds and Low Coordination in Phosphorus Chemistry, ed. M. Regitz and O. J. Scherer, Georg Thieme Verlag, Sttugart, 1990
3. Nucleophilic Phosphinidene Complexes: Access and Applicability
4. Metal-phosphido and -phosphinidene complexes in P–E bond-forming reactions
5. Developing the chemistry of monovalent phosphorus
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