One-step synthesis and P–H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives-Reference-Cited by-同舟云学术

One-step synthesis and P–H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives

Published:2019 Issue:39 Volume:48 Page:14585-14589
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Alvarez M. Angeles¹²³⁴,Burgos Mónica¹²³⁴,García M. Esther¹²³⁴^ORCID,García-Vivó Daniel¹²³⁴^ORCID,Ruiz Miguel A.¹²³⁴^ORCID,Vega Patricia¹²³⁴

Affiliation:

1. Departamento de Química Orgánica e Inorgánica/IUQOEM

2. Universidad de Oviedo

3. E33071 Oviedo

4. Spain

Abstract

Photolysis, deprotonation and one-electron reduction enable the title complex to render new phosphinidene derivatives with heterometallic Mo–P–M cores (M = Re, Fe, Au).

Funder

Ministerio de Economía y Competitividad

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02382H

Reference27 articles.

1. Phosphinidene-bridged binuclear complexes

2. Phosphinidene complexes and their higher homologs