Pd-catalyzed ortho-C–H arylation of free anilines with arylboric acids forming o-amino biaryls

Author:

Lin Ying1,Ye Changxu1,Zhou Meng1,Tang Zhi1ORCID,Liu Long1ORCID,Wang Yuansheng1,Wang Lingling1,Chen Tieqiao1ORCID

Affiliation:

1. Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chem, Hainan Provincial Fine Chemical Engineering Research Center, Hainan University, Haikou, 570228, China

Abstract

Pd-catalyzed o-C–H arylation of anilines with arylboric acids is reported, which enables a wide range of arylboric acids to couple with free anilines to produce o-amino biaryls in moderate to good yields with good functional group tolerance.

Funder

National Natural Science Foundation of China

Key Research and Development Project of Hainan Province

Natural Science Foundation of Hainan Province

Publisher

Royal Society of Chemistry (RSC)

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