The atomic level mechanism of white phosphorous demolition by di-iodine
Author:
Affiliation:
1. Istituto di Chimica dei Composti Organometallici – Consiglio Nazionale delle Ricerche (CNR-ICCOM)
2. Sesto Fiorentino
3. Italy
Abstract
Multi-step reaction ofI2withP4occurs through dynamic halogen bonding evolutions to affordPI3molecules. Eachconcertedstep involves two I–I* diatomics with 3 + 3 bond breakings (one P–P and two I–I*) and makings (two P–I and one I*–I*), while organo-susbtituted P atoms behave differently.
Funder
H2020 European Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04034B
Reference79 articles.
1. D. E. C. Corbridge , The structural Chemistry of Phosphorus , Elsevier , Amsterdam, NL , 1974
2. The Extended Stability Range of Phosphorus Allotropes
3. P4 Activation by Late-Transition Metal Complexes
4. Synthesis of Exceptionally Stable Iron and Rutheniumη1-tetrahedro-Tetraphosphorus Complexes: Evidence for a Strong Temperature Dependence of M−P4 π Back Donation
5. Coordination chemistry and functionalization of white phosphorus via transition metal complexes
Cited by 18 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Schrittweiser Abbau von weißem Phosphor: Experimentelle und computergestützte Studien zum Mechanismus der P4‐Hydrostannylierung;Angewandte Chemie;2024-09-12
2. Unravelling White Phosphorus: Experimental and Computational Studies Reveal the Mechanisms of P4 Hydrostannylation;Angewandte Chemie International Edition;2024-09-12
3. Halogen-Bonding-Mediated Radical Reactions: The Unexpected Behavior of Piperazine-Based Dithiooxamide Ligands in the Presence of Diiodine;Inorganic Chemistry;2023-01-05
4. Halogenation of heterobimetallic triple-decker complexes containing an E5 middle deck (E = P, As);Polyhedron;2022-07
5. Halogenation of the Hexaphosphabenzene Complex [(Cp*Mo) 2 (μ,η 6 :η 6 ‐P 6 )]: Snapshots on the Reaction Progress;Chemistry – A European Journal;2022-04-21
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3