Electron transfer within β-diketiminato nickel bromide and cobaltocene redox couples activating CO2-Reference-Cited by-同舟云学术

Electron transfer within β-diketiminato nickel bromide and cobaltocene redox couples activating CO2

Published:2021 Issue:7 Volume:57 Page:875-878
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zimmermann Philipp¹²³⁴,Kilpatrick Alexander F. R.¹²³⁴^ORCID,Ar Deniz¹²³⁴,Demeshko Serhiy⁵⁶⁷⁸⁴,Cula Beatrice¹²³⁴^ORCID,Limberg Christian¹²³⁴^ORCID

Affiliation:

1. Humboldt-Universität zu Berlin, Institut für Chemie

2. Brook-Taylor-Str. 2

3. 12489 Berlin

4. Germany

5. Universität Göttingen

6. Institut für Anorganische Chemie

7. Tammannstr. 4

8. D-37077 Göttingen

Abstract

Even though β-diketiminato nickel(ii) bromide and cobaltocene have nearly identical redox potentials the corresponding electron transfer complex can be crystallised from the equilibrium and activates CO₂ to form a mononuclear nickel(ii) carbonate.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D0CC06983C

Reference28 articles.

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3. N2 Activation in NiI-NN-NiI Units: The Influence of Alkali Metal Cations and CO Reactivity

4. A Dinuclear Nickel(I) Dinitrogen Complex and its Reduction in Single-Electron Steps

5. Reversible P4Activation with Nickel(I) and an Î·3-Coordinated Tetraphosphorus Ligand between Two NiICenters

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