Electrocatalyst decomposition pathways: torsional strain in a second sphere proton relay shuts off CO<sub>2</sub>RR in a Re(2,2′-bipyridyl)(CO)<sub>3</sub>X type electrocatalyst-Reference-Cited by-同舟云学术

Electrocatalyst decomposition pathways: torsional strain in a second sphere proton relay shuts off CO₂RR in a Re(2,2′-bipyridyl)(CO)₃X type electrocatalyst

Published:2022 Issue:45 Volume:51 Page:17381-17390
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dubrawski Zachary S.¹^ORCID,Chang Chia Yun¹,Carr Cody R.¹^ORCID,Gelfand Benjamin S.¹^ORCID,Piers Warren E.¹^ORCID

Affiliation:

1. University of Calgary, Department of Chemistry, 2500 University Drive N.W., Calgary, Alberta, T2N 1N4, Canada

Abstract

Group 7 tris(carbonyl) bipyridine complexes have been well explored as important CO2 reduction reaction (CO2RR) electrocatalysts and now represent an excellent platform for catalyst design.

Funder

Canada First Research Excellence Fund

Canada Research Chairs

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02876J

Reference53 articles.

1. Transition Metal Complexes as Catalysts for the Electroconversion of CO 2 : An Organometallic Perspective

2. Electrocatalytic reduction of carbon dioxide mediated by Re(bipy)(CO)3Cl (bipy = 2,2′-bipyridine)

3. Redox catalysis in organic electrosynthesis: basic principles and recent developments

4. Synthetic Organic Design for Solar Fuel Systems

5. Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes

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