Direct observation of highly effective hydrogen isotope separation at active metal sites by <i>in situ</i> DRIFT spectroscopy-Reference-Cited by-同舟云学术

Direct observation of highly effective hydrogen isotope separation at active metal sites by in situ DRIFT spectroscopy

Published:2023 Issue:26 Volume:59 Page:3922-3925
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yan Xiayan¹,Song Yaqi¹,Wang Degao¹,Xia Tifeng¹^ORCID,Tan Xinxin¹,Ba Jingwen¹,Tang Tao¹^ORCID,Luo Wenhua²,Sang Ge¹,Xiong Renjin¹^ORCID

Affiliation:

1. Institute of Materials, China Academy of Engineering Physics, P. O. Box 9071-12, Mianyang 621907, China

2. Science and Technology on Surface Physics and Chemistry Laboratory, P. O. Box 9072-35, Mianyang 621908, China

Abstract

In situ DRIFT spectroscopy was developed to observe the preferential adsorption of D2 over H2 at active CuI sites to show the chemical affinity quantum sieving effect for hydrogen isotope separation in microporous adsorbents.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

China Academy of Engineering Physics

Science and Technology on Surface Physics and Chemistry Laboratory

National Safety Academic Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC00522D

Reference35 articles.

1. Hydrogen Isotope Separation in Confined Nanospaces: Carbons, Zeolites, Metal–Organic Frameworks, and Covalent Organic Frameworks

2. Barely porous organic cages for hydrogen isotope separation

3. Quantum sieving: feasibility and challenges for the separation of hydrogen isotopes in nanoporous materials

4. Quantum Sieving for Separation of Hydrogen Isotopes Using MOFs

5. Highly Effective Hydrogen Isotope Separation in Nanoporous Metal–Organic Frameworks with Open Metal Sites: Direct Measurement and Theoretical Analysis

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