Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion-Reference-Cited by-同舟云学术

Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

Published:2016 Issue:3 Volume:7 Page:1815-1818
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Luo Ming¹²³⁴⁵,Zhu Congqing¹²³⁴⁵,Chen Lina¹²³⁴⁵,Zhang Hong¹²³⁴⁵,Xia Haiping¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM)

2. Department of Chemistry

3. College of Chemistry and Chemical Engineering

4. Xiamen University

5. Xiamen 361005

Abstract

The halogenation of metallapentalyne led to the formation of metallapentalenes. Experimental and computational studies indicate that four resonance structures, including the first examples of metallaiodirenium and metallabromirenium ions, contribute to the overall structure of the complexes.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC03963K

Reference48 articles.

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3. X-Ray structure of bridged 2,2′-bi(adamant-2-ylidene) chloronium cation and comparison of its reactivity with a singly-bonded chloroarenium cation