The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes
Author:
Affiliation:
1. Department of Chemistry
2. School of Life Sciences
3. University of Sussex
4. Brighton BN1 9QJ
5. UK
Abstract
ThIV/ThIII reduction wave in the cyclic voltammogram of [Th(η-C5H3{SiMe3}2)3Cl].
Funder
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01553A
Reference24 articles.
1. The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C5H3(SiMe3)2}3]; the first thorium(III) crystal structure
2. Synthesis and Characterization of the First Sandwich Complex of Trivalent Thorium: A Structural Comparison with the Uranium Analogue
3. Synthesis, properties and structures of the tris(cyclopentadienyl)thorium(III) complexes [Th{η5-C5H3(SiMe2R)2-1,3}3] (R=Me or tBu)
4. Importance of Energy Level Matching for Bonding in Th3+-Am3+ Actinide Metallocene Amidinates, (C5Me5)2[iPrNC(Me)NiPr]An
5. Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η5-C5Me3H(CH2)-κC]2– Tuck-over Ligands in a Tetrathorium Octahydride Complex
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