Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η5-C5Me3H(CH2)-κC]2– Tuck-over Ligands in a Tetrathorium Octahydride Complex-Reference-Cited by-同舟云学术

Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η5-C5Me3H(CH2)-κC]2– Tuck-over Ligands in a Tetrathorium Octahydride Complex

Published:2013-10-23 Issue:21 Volume:32 Page:6522-6531
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Siladke Nathan A.¹,Webster Christopher L.¹,Walensky Justin R.¹,Takase Michael K.¹,Ziller Joseph W.¹,Grant Daniel J.²,Gagliardi Laura²,Evans William J.¹

Affiliation:

1. Department of Chemistry, University of California Irvine, California 92697, United States

2. Department of Chemistry, Chemical Theory Center, and Supercomputing Institute, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, United States

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om4008482

Reference81 articles.

1. Bis(pentamethylcyclopentadienyl)actinide alkyls: facile activation of carbon monoxide, carbon-carbon double bond formation, and the production of unusual oxygen-bonded migratory insertion products

2. Bis(pentamethylcyclopentadienyl)actinide chemistry: properties of stable thorium and uranium dialkyls and hydrides

3. Molecular Structure of an Unusual Organoactinide Hydride Complex Determined Solely by Neutron Diffraction

4. Multi-Electron Reduction from Alkyl/Hydride Ligand Combinations in U4+Complexes

5. The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C5H3(SiMe3)2}3]; the first thorium(III) crystal structure

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