Highly diastereo- and enantioselective organocatalytic synthesis of trifluoromethylated erythritols based on the in situ generation of unstable trifluoroacetaldehyde-Reference-Cited by-同舟云学术

Highly diastereo- and enantioselective organocatalytic synthesis of trifluoromethylated erythritols based on the in situ generation of unstable trifluoroacetaldehyde

Published:2021 Issue:6 Volume:19 Page:1296-1304
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Funabiki Kazumasa¹²³⁴^ORCID,Gotoh Toshiya¹²³⁴,Kani Ryunosuke¹²³⁴,Inuzuka Toshiyasu⁵⁶²³⁴,Kubota Yasuhiro¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biomolecular Science

2. Gifu University

3. Gifu 501-1193

4. Japan

5. Division of Instrumental Analysis

6. Life Science Research Centre

Abstract

A highly diastereo- and enantioselective organocatalytic method to synthesise erythritols bearing a trifluoromethyl group has been investigated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D0OB02067B

Reference48 articles.

1. Erythritol Attenuates Postprandial Blood Glucose by Inhibiting α-Glucosidase

2. Diastereoselective Passerini Reaction of Biobased Chiral Aldehydes: Divergent Synthesis of Various Polyfunctionalized Heterocycles

3. A General Strategy for the Discovery of Metabolic Pathways: d-Threitol, l-Threitol, and Erythritol Utilization in Mycobacterium smegmatis

4. Synthesis of Methylerythritol Phosphate Analogues and Their Evaluation as Alternate Substrates for IspDF and IspE from Agrobacterium tumefaciens

5. Efficient asymmetric organocatalytic formation of erythrose and threose under aqueous conditions

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