Chiral self-recognition in a bispericyclic cyclodimerisation reaction of 1-azadienes

Author:

López-Francés Adrián1ORCID,del Corte Xabier1ORCID,Serna-Burgos Zuriñe1ORCID,de los Santos Jesús M.1ORCID,de Cózar Abel23ORCID,Vicario Javier1ORCID

Affiliation:

1. Department of Organic Chemistry I, Faculty of Pharmacy, University of the Basque Country, UPV/EHU, Paseo de la Universidad 7, 01006 Vitoria-Gasteiz, Spain

2. Department of Organic Chemistry I, Donostia International Physics Centre (DIPC), University of the Basque Country, UPV/EHU, Paseo Manuel de Lardizabal, 3, 20018 Donostia-San Sebastián, Spain

3. Ikerbasque, Basque Foundation for Science, Plaza Euskadi 5, 48009, Bilbao, Spain

Abstract

Hermaphroditism of molecules: as in nature some species behave as male or female depending on the environment, herein we report a bispericyclic dimerisation where a molecule behaves as diene or dienophile, depending on its location at the TS.

Funder

Eusko Jaurlaritza

Ministerio de Ciencia, Innovación y Universidades

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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