α-C–C agostic interactions and C–H bond activation in scandium cyclopropyl complexes-Reference-Cited by-同舟云学术

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α-C–C agostic interactions and C–H bond activation in scandium cyclopropyl complexes

Published:2020 Issue:24 Volume:7 Page:4822-4831
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Xu Cheng¹²³⁴⁵,Li Guangyu¹²³⁴⁵,Etienne Michel⁶⁷⁸⁹¹⁰^ORCID,Leng Xuebing¹²³⁴⁵,Chen Yaofeng¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Organometallic Chemistry

2. Shanghai Institute of Organic Chemistry

3. University of Chinese Academy of Sciences

4. Chinese Academy of Sciences

5. Shanghai 200032

6. LCC-CNRS

7. Université de Toulouse

8. CNRS

9. UPS

10. 31077 Toulouse Cedex 4

Abstract

Electron deficient scandium cyclopropyl complexes have been synthesized and fully characterized for the first time, and a combination of solid XRD, solution NMR and theoretical studies well demonstrated the α-C–C agostic interactions in the complexes.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Program of Shanghai Academic Research Leader

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QI/D0QI01163K

Reference35 articles.

1. Bonding Properties of Cyclopropane and Their Chemical Consequences

2. Bent Bonds in Organic Compounds

3. Photoelectron Spectra of Cyclopropane and Cyclopropene Compounds

4. Introduction: Cyclopropanes and Related Rings

5. Intramolecular C–C agostic complexes: C–C sigma interactions by another name

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