Affiliation:
1. CNRS/Université Paul Sabatier Laboratoire Hétérochimie Fondamentale et Appliquée (LHFA, UMR 5069) 118 Route de Narbonne 31062 Toulouse Cedex 09 France).
2. Centre for Materials Science and Nanotechnology University of Oslo P.O. Box 1126 Blindern, N-0316 Oslo Norway
3. Department of Chemistry University of Oslo P.O. Box 1033 Blindern, N-0315 Oslo Norway
Abstract
Abstractπ‐Allyl complexes of transition metals are key species in organometallic chemistry and homogeneous catalysis. Palladium(II) π‐allyl complexes in particular, have gained a lot of attention, but their isoelectronic gold(III) counterparts long remained elusive. However, this situation changed during the last few years. This concept article describes the preparative routes, characterization, structure and reactivity of such species, together with their catalytic applications. The influence of the ancillary ligand at gold, either (P,C)/(N,C)‐cyclometalated or (P,N)‐hemilabile, is analysed in detail. The Au(III) and Pd(II) π‐allyl complexes are also compared to highlight the similarities and differences.
Funder
Centre National de la Recherche Scientifique
Agence Nationale de la Recherche
Norges Forskningsråd
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis
Cited by
1 articles.
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