TMSCFX2 (X = Cl, Br) as halofluorocarbene sources for the synthesis of halofluorocyclopropanes-Reference-Cited by-同舟云学术

TMSCFX2 (X = Cl, Br) as halofluorocarbene sources for the synthesis of halofluorocyclopropanes

Published:2021 Issue:3 Volume:57 Page:319-322
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Chen Dingben¹²³⁴⁵^ORCID,Fan Zili¹²³⁴⁵,Huang Ling⁶⁷⁸⁹,Gao Kaili⁶⁷⁸⁹,Xiao Pan¹²³⁴⁵,Ni Chuanfa¹²³⁴⁵^ORCID,Hu Jinbo¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Organofluorine Chemistry

2. Center for Excellence in Molecular Synthesis

3. Shanghai Institute of Organic Chemistry

4. Chinese Academy of Sciences

5. Shanghai

6. School of Pharmaceutical and Materials Engineering

7. Taizhou University

8. Taizhou

9. China

Abstract

The [2+1] cycloaddition reactions of novel halofluorocarbene reagents [Me₃SiCFX₂ (X = Cl, Br)] with alkenes have been disclosed.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D0CC06004F

Reference46 articles.

1. K. L. Kirk , S.Yoshida and G.Haufe , in Fluorine and Health: Molecular Imaging, Biomedical Materials and Pharmaceuticals , ed. A. Tressaud and G. Haufe , Elsevier , Amsterdam , 2008 , ch. 15, pp. 661–697

2. Syntheses and Applications of Monofluorinated Cyclopropanes

3. Stereoselective Cyclopropanation Reactions

4. Recent developments in asymmetric cyclopropanation

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