Gd(iii)–Gd(iii) EPR distance measurements – the range of accessible distances and the impact of zero field splitting

Author:

Dalaloyan Arina1234,Qi Mian5678,Ruthstein Sharon91011124,Vega Shimon1234,Godt Adelheid5678,Feintuch Akiva1234,Goldfarb Daniella1234

Affiliation:

1. Department of Chemical Physics

2. Weizmann Institute of Science

3. Rehovot

4. Israel

5. Bielefeld University

6. Faculty of Chemistry and Center for Molecular Materials

7. D-33615 Bielefeld

8. Germany

9. Department of Chemistry

10. Faculty of Exact Sciences

11. Bar-Ilan University

12. Ramat Gan

Abstract

Gd rulers were designed in the 2–8 nm range for in-depth evaluation of Gd(iii) complexes as spin labels for EPR distance measurements.

Funder

United States - Israel Binational Science Foundation

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference59 articles.

1. G. Jeschke , in Structural Information from Spin-Labels and Intrinsic Paramagnetic Centres in the Biosciences, ed. C. R. Timmel and J. R. Harmer, Struct Bonding, Springer Berlin Heidelberg, 2013, vol. 152, pp. 83–120

2. Long-range distance determinations in biomacromolecules by EPR spectroscopy

3. P. P. Borbat and J. H.Freed, in Structural Information from Spin-Labels and Intrinsic Paramagnetic Centres in the Biosciences, ed. C. R. Timmel and J. R. Harmer, Struct. Bonding, Springer Berlin Heidelberg, 2013, vol. 152, pp. 1–82

4. EPR Spectroscopy: Applications in Chemistry and Biology, ed. M. Drescher and G. Jeschke, Springer, 2012

5. The determination of pair distance distributions by pulsed ESR using Tikhonov regularization

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