Defect-stabilized and oxygen-coordinated iron single-atom sites facilitate hydrogen peroxide electrosynthesis

Author:

Gao Taotao12,Qiu Lu23,Xie Minghao4,Jin Zhaoyu5ORCID,Li Panpan1ORCID,Yu Guihua4ORCID

Affiliation:

1. College of Materials Science and Engineering, Sichuan University, Chengdu, 610065, P. R. China

2. Institute for Advanced Study, Chengdu University, Chengdu, 610106, P. R. China

3. College of Chemical Engineering, Sichuan University, Chengdu, 610065, P. R. China

4. Materials Science and Engineering Program and Walker Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712, USA

5. Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu, 610054, P. R. China

Abstract

Oxygen-coordinated iron single-atom sites (Fe–O4) modified with vacancy defects show high 2e-ORR catalytic performance. The Fe–O4 moiety is relevant to the selectivity and kinetic rate of the 2e pathway while vacancy defects enhance the stability.

Funder

National Natural Science Foundation of China

Camille and Henry Dreyfus Foundation

Welch Foundation

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrical and Electronic Engineering,Process Chemistry and Technology,Mechanics of Materials,General Materials Science

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