Easy-axis magnetic anisotropy in tetragonally elongated cobalt(<scp>ii</scp>) complexes beyond the spin-Hamiltonian formalism-Reference-Cited by-同舟云学术

Easy-axis magnetic anisotropy in tetragonally elongated cobalt(ii) complexes beyond the spin-Hamiltonian formalism

Published:2023 Issue:23 Volume:52 Page:7885-7892
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mičová Romana¹^ORCID,Rajnák Cyril¹^ORCID,Titiš Ján¹^ORCID,Bieńko Alina²^ORCID,Moncoľ Ján³^ORCID,Samoľová Erika⁴^ORCID,Boča Roman¹^ORCID

Affiliation:

1. Department of Chemistry, Faculty of Natural Sciences, University of SS Cyril and Methodius, 917 01 Trnava, Slovakia

2. Faculty of Chemistry, University of Wroclaw, 14 F. Joliot-Curie, 50-383 Wroclaw, Poland

3. Institute of Inorganic Chemistry, Slovak University of Technology, 812 37 Bratislava, Slovakia

4. Institute of Physics of the Czech Academy of Sciences, 182 21 Prague, Czech Republic

Abstract

Complexes under study exhibit field-supported SMR. For 1, the relaxation time at T = 2.0 K is τHF = 20 and 2 ms at the applied field BDC = 0.15 and 0.35 T, respectively. For 2 at T = 2.0 K and BDC = 0.1 T, the relaxation time is τHF = 6 ms.

Funder

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Agentúra na Podporu Výskumu a Vývoja

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00990D

Reference46 articles.

1. Zero-field splitting in metal complexes

2. Applying Unconventional Spectroscopies to the Single‐Molecule Magnets, Co(PPh 3 ) 2 X 2 (X=Cl, Br, I): Unveiling Magnetic Transitions and Spin‐Phonon Coupling

3. Quantum coherence in a processable vanadyl complex: new tools for the search of molecular spin qubits

4. How do phonons relax molecular spins?

5. A low spin manganese(iv) nitride single molecule magnet

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Coordination number impact on magnetic properties of Schiff base Co(II) complexes;Polyhedron;2024-09

2. Halide mediated modulation of magnetic interaction and anisotropy in dimeric Co(ii) complexes;Dalton Transactions;2024

3. Coordination Number Impact on Magnetic Properties of Schiff Base Co(Ii) Complexes;2024