A low spin manganese(iv) nitride single molecule magnet

Author:

Ding Mei1234,Cutsail III George E.1564,Aravena Daniel7891011,Amoza Martín1213141516,Rouzières Mathieu1718192021,Dechambenoit Pierre1718192021,Losovyj Yaroslav1234,Pink Maren1234,Ruiz Eliseo1213141516,Clérac Rodolphe1718192021,Smith Jeremy M.1234

Affiliation:

1. Department of Chemistry

2. Indiana University

3. Bloomington

4. USA

5. Northwestern University

6. Evanston

7. Departamento de Química de los Materiales

8. Facultad de Química y Biología

9. Universidad de Santiago de Chile (USACH)

10. Santiago

11. Chile

12. Departament de Química Inorgànica

13. Institut de Recerca de Química Teòrica i Computacional

14. Universitat de Barcelona

15. Barcelona

16. 08028 Spain

17. CNRS

18. CRPP

19. UPR 8641

20. F-33600 Pessac

21. France

Abstract

Structural, spectroscopic and magnetic methods have been used to characterize the tris(carbene)borate compound PhB(MesIm)3MnN as a four-coordinate manganese(iv) complex with a low spin (S = 1/2) configuration.

Funder

Institució Catalana de Recerca i Estudis Avançats

Centre National de la Recherche Scientifique

Comisión Nacional de Investigación Científica y Tecnológica

National Science Foundation

National Institutes of Health

U.S. Department of Energy

Ministerio de Economía y Competitividad

Indiana University

University of Bordeaux

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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