The influence of the <i>trans</i>-ligand to NO on the thermal stability of the photoinduced side-bond coordinated linkage isomer-Reference-Cited by-同舟云学术

The influence of the trans-ligand to NO on the thermal stability of the photoinduced side-bond coordinated linkage isomer

Published:2022 Issue:26 Volume:46 Page:12641-12650
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Mikhailov Artem A.¹^ORCID,Kostin Gennadiy A.¹^ORCID,Schaniel Dominik²^ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Avenue, Novosibirsk 630090, Russian Federation

2. Université de Lorraine, CNRS, CRM2, UMR 7036, Nancy 54000, France

Abstract

The influence of trans-to-NO ligand (X) on the thermal stability of transient side-on coordinated nitrosyl linkage isomer (MS2) is investigated in a series of trans-[RuNOPy4X](PF6)2 (X = F− (RuF), Cl− (RuCl), Br− (RuBr) and OH− (RuOH)) compounds.

Funder

Russian Science Foundation

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ01388F

Reference50 articles.

1. Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex

2. The First Photocrystallographic Evidence for Light-Induced Metastable Linkage Isomers of Ruthenium Sulfur Dioxide Complexes