Local force constants and charges of the nitrosyl ligand in photoinduced NO linkage isomers in a prototypical ruthenium nitrosyl complex-Reference-Cited by-同舟云学术

Local force constants and charges of the nitrosyl ligand in photoinduced NO linkage isomers in a prototypical ruthenium nitrosyl complex

Published:2024 Issue:21 Volume:26 Page:15255-15267
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Mikhailov Artem A.¹,Gansmüller Axel¹,Konieczny Krzysztof A.¹²,Pillet Sébastien¹,Kostin Gennadiy³^ORCID,Klüfers Peter⁴,Woike Theo¹,Schaniel Dominik¹^ORCID

Affiliation:

1. Université de Lorraine, CNRS, CRM2, 54000 Nancy, France

2. Faculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland

3. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, Novosibirsk 630090, Russia

4. Department of Chemistry, Ludwig-Maximilians-Universität, Butenandtstrasse 5–13, München 81377, Germany

Abstract

Photoinduced NO linkage isomers: total charges on NO are not correlated to the frequency of the NO stretching vibration. Local force constants reveal a significant change in coupling of Ru–N/O and N–O stretching vibrations.

Funder

Russian Science Foundation

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP01374C

Reference66 articles.

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5. Photoswitchable coordination compounds