Structural snapshots of an Al–Cu bond-mediated transformation of terminal acetylenes-Reference-Cited by-同舟云学术

Structural snapshots of an Al–Cu bond-mediated transformation of terminal acetylenes

Published:2023 Issue:11 Volume:14 Page:2866-2876
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liu Han-Ying¹,Neale Samuel E.¹^ORCID,Hill Michael S.¹^ORCID,Mahon Mary F.¹,McMullin Claire L.¹

Affiliation:

1. Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK

Abstract

The C–Al bond of [{SiNDipp}Al–Cu(NHCiPr)] reacts sequentially with three equivalents of terminal alkyne to provide cuprous (hydrido)(alkynyl)aluminate, (E-alkenyl)(alkynyl)aluminate and bis(alkynyl)aluminate derivatives.

Funder

Engineering and Physical Sciences Research Council

University of Bath

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00240C

Reference65 articles.

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