A bench stable formal Cu(iii) N-heterocyclic carbene accessible from simple copper(ii) acetate
Author:
Affiliation:
1. School of Chemistry
2. Damghan University
3. Damghan 36715-364
4. Iran
5. Molecular Catalysis
6. Catalysis Research Center and Faculty of Chemistry
7. Technische Universität München
8. D-85747 Garching bei München
9. Germany
Abstract
The first stable formal Cu(iii) NHC and its unusual reactivity with acetate are reported. Several products of this reaction are identified and fully characterised. It reactivity is extensively investigated and additionally explored by means of theoretical, electrochemical and isotope labelling experiments.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01834K
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