X-ray absorption and emission spectroscopy of N<sub>2</sub>S<sub>2</sub> Cu(<scp>ii</scp>)/(<scp>iii</scp>) complexes-Reference-Cited by-同舟云学术

X-ray absorption and emission spectroscopy of N₂S₂ Cu(ii)/(iii) complexes

Published:2024 Issue:18 Volume:53 Page:7828-7838
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Geoghegan Blaise L.¹²³^ORCID,Bilyj Jessica K.⁴^ORCID,Bernhardt Paul V.⁴^ORCID,DeBeer Serena¹^ORCID,Cutsail George E.¹²^ORCID

Affiliation:

1. Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470 Mülheim an der Ruhr, Germany

2. Institute of Inorganic Chemistry, University of Duisburg-Essen, Universitätsstrasse 5-7, 45117 Essen, Germany

3. Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, W12 0BZ, London, UK

4. School of Chemistry and Molecular Biosciences, University of Queensland, Brisbane 4072, Australia

Abstract

The competing influences of both oxidation state and ligand protonation state in Cu(ii) and Cu(iii) Schiff base complexes are explored through copper K-edge X-ray absorption and valence-to-core emission spectroscopies along with DFT calculations.

Funder

Max-Planck-Gesellschaft

European Research Council

Helmholtz-Zentrum Berlin für Materialien und Energie

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00085D

Reference83 articles.

1. A bench stable formal Cu(iii) N-heterocyclic carbene accessible from simple copper(ii) acetate

2. An Adaptable N‐Heterocyclic Carbene Macrocycle Hosting Copper in Three Oxidation States

3. Cu(iii)–bis-thiolato complex forms an unusual mono-thiolato Cu(iii)–peroxido adduct

4. Highly stabilized copper(III) complexes

5. Characterization of a readily accessible copper(III)-peptide complex

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