A cyano and end-to-end azido bridged 3D copper(ii)–copper(i) mixed-valence coordination polymer and its transformation to copper nitride nanoparticles-Reference-Cited by-同舟云学术

A cyano and end-to-end azido bridged 3D copper(ii)–copper(i) mixed-valence coordination polymer and its transformation to copper nitride nanoparticles

Published:2014 Issue:64 Volume:4 Page:34110-34116
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Trivedi Manoj¹²³,Singh Gurmeet¹²³,Kumar Abhinav¹⁴⁵⁶,Rath Nigam P.⁷⁸⁹¹⁰

Affiliation:

1. Department of Chemistry

2. University of Delhi

3. Delhi-110007, INDIA

4. Faculty of Science

5. University of Lucknow

6. Lucknow-226 007, India

7. Department of Chemistry & Biochemistry and Centre for Nanoscience

8. University of Missouri-St. Louis

9. One University Boulevard

10. St. Louis, USA

Abstract

Syntheses and characterization of a CN and end-to-end N₃ bridged three-dimensional Cu(II)–Cu(I) mixed valence polymer (1), with Cu-N₃ system without CN (2) and a CN-bridged Cu analogue without N₃ (3) are reported and solid-state transformation of the 1 to copper nitride nanoparticles performed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA05980H

Reference80 articles.

1. Nickel(II) Chain with Alternating End-On/End-to-End Single Azido Bridges: A Combined Structural, Magnetic, and Theoretical Study

2. A two-dimensional azido-based topologic ferrimagnet

3. From Achiral Ligands to Chiral Coordination Polymers: Spontaneous Resolution, Weak Ferromagnetism, and Topological Ferrimagnetism

4. A Unique 3D Alternating Ferro- and Antiferromagnetic Manganese Azide System with Threefold Interpenetrating (10,3) Nets

5. Single-Molecule Magnets: A Mn25 Complex with a Record S = 51/2 Spin for a Molecular Species

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