Stable and reactive diacetyliminoxyl radical in oxidative C–O coupling with β-dicarbonyl compounds and their complexes

Author:

Budnikov Alexander S.1ORCID,Krylov Igor B.12ORCID,Lastovko Andrey V.13,Paveliev Stanislav A.1,Romanenko Alexander R.2,Nikishin Gennady I.1,Terent'ev Alexander O.12ORCID

Affiliation:

1. N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, 47 Leninsky prosp., Moscow 119991, Russian Federation

2. D.I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya sq., Moscow 125047, Russian Federation

3. M. V. Lomonosov Moscow State University, 1 Leninskie Gory, Moscow 119991, Russian Federation

Abstract

Between oxime radicals, which were generally considered as unstable intermediates, one of the simplest was found to be a storable, synthetically available, and useful reagent.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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