Efficient radical C(sp3)–H α-oxyamination of carbonyls adjacent to the carbon chalcogen bond

Author:

Wang Man1,Wang Rui1,Zhang Long2,Si Wen1,Song Ran1,Yang Daoshan1ORCID,Lv Jian1ORCID

Affiliation:

1. Key Laboratory of Optic-electric Sensing and Analytic Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042, China

2. Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing 100084, China

Abstract

An efficient radical C(sp3)–H α-oxyamination of carbonyls adjacent to different chalcogens (e.g., S, O, and Se) at the α-position is demonstrated.

Funder

Taishan Scholar Foundation of Shandong Province

Natural Science Fund for Distinguished Young Scholars of Shandong Province

Science and Technology Support Plan for Youth Innovation of Colleges and Universities of Shandong Province of China

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Qingdao University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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1. Organic Synthesis Using Nitroxides;Chemical Reviews;2023-08-14

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