Using internal electrostatic fields to manipulate the valence manifolds of copper complexes-Reference-Cited by-同舟云学术

Using internal electrostatic fields to manipulate the valence manifolds of copper complexes

Published:2021 Issue:12 Volume:12 Page:4395-4404
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Weberg Alexander B.¹²³⁴⁵,McCollom Samuel P.¹²³⁴⁵,Thierer Laura M.¹²³⁴⁵,Gau Michael R.¹²³⁴⁵,Carroll Patrick J.¹²³⁴⁵,Tomson Neil C.¹²³⁴⁵^ORCID

Affiliation:

1. Roy and Diana Vagelos Laboratories

2. Department of Chemistry

3. University of Pennsylvania

4. Philadelphia

5. USA

Abstract

Secondary coordination sphere electrostatic effects tune the valence manifolds of copper centers, impacting molecular geometries, photophysical properties, and redox potentials.

Funder

National Institutes of Health

Pittsburgh Foundation

University of Pennsylvania

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06364A

Reference52 articles.

1. Electrostatic Basis for Enzyme Catalysis

2. Extreme electric fields power catalysis in the active site of ketosteroid isomerase

3. Electrostatic control of photoisomerization pathways in proteins

4. Electric Fields and Enzyme Catalysis

5. Measurement of Electric Fields Experienced by Urea Guest Molecules in the 18-Crown-6/Urea (1:5) Host–Guest Complex: An Experimental Reference Point for Electric-Field-Assisted Catalysis

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