The influence of nitrogen doping of the acceptor in orange-red thermally activated delayed fluorescence emitters and OLEDs

Author:

Si Changfeng1ORCID,Hu Ya-Nan2ORCID,Sun Dianming1ORCID,Wang Kai2ORCID,Zhang Xiao-Hong23ORCID,Zysman-Colman Eli1ORCID

Affiliation:

1. Organic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews, St Andrews KY16 9ST, UK

2. Institute of Functional Nano & Soft Materials (FUNSOM), Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou, Jiangsu 215123, P. R. China

3. Jiangsu Key Laboratory of Advanced Negative Carbon Technologies, Soochow University, Suzhou, 215123, Jiangsu, P. R. China

Abstract

We have developed a family of four orange-to-red TADF compounds whose structures differ by the number of nitrogen atoms contained within the acceptor. It was found that increasing the nitrogen atom content results in a more stabilized LUMO, a smaller ΔESTand fasterkRISC.

Funder

China Scholarship Council

Engineering and Physical Sciences Research Council

National Natural Science Foundation of China

Royal Academy of Engineering

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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