Evaluation of acenes as potential acceptors in thermally activated delayed fluorescence emitters and the promise of a phenoxazine–naphthalene emitter for OLEDs

Author:

Lee Oliver S.12ORCID,Sharma Nidhi12,Matulaitis Tomas1ORCID,Slawin Alexandra M. Z.1ORCID,Olivier Yoann3ORCID,Samuel Ifor D. W.2ORCID,Gather Malte C.24ORCID,Zysman-Colman Eli1ORCID

Affiliation:

1. Organic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, UK

2. Organic Semiconductor Centre, SUPA School of Physics and Astronomy, University of St Andrews, St Andrews, KY16 9SS, UK

3. Laboratory for Chemistry of Novel Materials, University of Mons-Hainaut, Place du Parc 20, B-7000 Mons, Belgium

4. Humboldt Centre for Nano- and Biophotonics, Department of Chemistry, University of Cologne, Greinstr. 4-6, 50939 Köln, Germany

Abstract

Linear acenes, such as naphthalene, can act as acceptors in donor–acceptor type TADF emitters. We demonstrate this strategy through a computational screen and by synthesizing a novel diphenoxazine-substituted naphthalene TADF emitter.

Funder

Fonds De La Recherche Scientifique - FNRS

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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