CO substitution by PPh3 in Fe2S2(CO)6 proceeds via a novel Fe2S intermediate-Reference-Cited by-同舟云学术

CO substitution by PPh3 in Fe2S2(CO)6 proceeds via a novel Fe2S intermediate

Published:2021 Issue: Volume: Page:
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhang Fanjun¹²³⁴⁵^ORCID,Woods Toby J.⁵⁶⁷⁸,Rauchfuss Thomas B.⁵⁶⁷⁸^ORCID,Arrigoni Federica⁹¹⁰¹¹¹²¹³,Zampella Giuseppe⁹¹⁰¹¹¹²¹³^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Qufu Normal University

3. Qufu

4. China

5. School of Chemical Sciences

6. University of Illinois at Urbana-Champaign

7. Urbana

8. USA

9. Department of Biotechnology and Biosciences

10. University of Milano-Bicocca

11. Piazza della Scienza 2

12. Milan-20126

13. Italy

Abstract

Substitution of CO ligands by PPh₃ in Fe₂(μ-S₂)(CO)₆ proceeds by a desulfurization–resulfurization sequence, generating SPPh₃ and Fe₂(μ-S)(CO)₆(PPh₃)₂ as intermediates. Protonation of Fe₂(μ-S)(CO)₆(PPh₃)₂ occurs at sulfur.

Funder

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC00956G

Reference21 articles.

1. [FeFe]-Hydrogenases: maturation and reactivity of enzymatic systems and overview of biomimetic models

2. P.Schollhammer and W.Weigand , Bioinspired Catalysis , Wiley-VCH , Weinheim , 2015

3. Catalytic Metallopolymers from [2Fe‐2S] Clusters: Artificial Metalloenzymes for Hydrogen Production

4. Chemical Versatility of [FeFe]-Hydrogenase Models: Distinctive Activity of [μ-C6H4-1,2-(κ2-S)2][Fe2(CO)6] for Electrocatalytic CO2 Reduction

5. Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Modulation of S‐Centered Reactivity: Impact of Terminal Ligands on Alkynyl Addition in [Fe₂(μ‐S₂)(CO)₄L₂] Complexes;European Journal of Inorganic Chemistry;2024-05-08

2. Isostructural bridging diferrous chalcogenide cores [Fe^II(μ-E)Fe^II] (E = O, S, Se, Te) with decreasing antiferromagnetic coupling down the chalcogenide series;Chemical Science;2023