Isostructural bridging diferrous chalcogenide cores [Fe<sup>II</sup>(μ-E)Fe<sup>II</sup>] (E = O, S, Se, Te) with decreasing antiferromagnetic coupling down the chalcogenide series-Reference-Cited by-同舟云学术

Isostructural bridging diferrous chalcogenide cores [Fe^II(μ-E)Fe^II] (E = O, S, Se, Te) with decreasing antiferromagnetic coupling down the chalcogenide series

Published:2023 Issue:24 Volume:14 Page:6770-6779
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zars Ethan¹^ORCID,Gravogl Lisa²^ORCID,Gau Michael R.¹,Carroll Patrick J.¹,Meyer Karsten²^ORCID,Mindiola Daniel J.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Pennsylvania, 231 S 34th St, Philadelphia, PA, 19104, USA

2. Department of Chemistry & Pharmacy, Friedrich-Alexander-Universität Erlangen – Nürnberg (FAU), Egerlandstr. 1, 91058 Erlangen, Bavaria, Germany

Abstract

Ferrous bridging mono-chalcogenide ate complexes K2[(tBupyrpyrr2)Fe2(μ-E)] (2-E) (E = O, S, Se, and Te) are prepared and show a Fe–E–Fe bridge from linear (E = O) to acute for E = Te, with lesser antiferromagnetic coupling going down the series.

Funder

University of Pennsylvania

Friedrich-Alexander-Universität Erlangen-Nürnberg

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01094E

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