Magnetic properties of the seven-coordinated nanoporous framework material Co(bpy)1.5(NO3)2 (bpy = 4,4′-bipyridine)-Reference-Cited by-同舟云学术

Magnetic properties of the seven-coordinated nanoporous framework material Co(bpy)1.5(NO3)2 (bpy = 4,4′-bipyridine)

Published:2012 Issue:34 Volume:41 Page:10382-10389
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bartolomé Elena¹²³,Alonso Pablo Javier⁴⁵⁶³,Arauzo Ana⁷⁸⁶³,Luzón Javier⁴⁵⁶³⁹,Bartolomé Juan⁴⁵⁶³,Racles Carmen¹⁰¹¹¹²,Turta Constantin¹⁰¹¹¹²¹³¹⁴

Affiliation:

1. Escola Universitària Salesiana de Sarrià

2. 08017-Barcelona

3. Spain

4. Instituto de Ciencia de Materiales de Aragón

5. CSIC-Universidad de Zaragoza

6. 50009 Zaragoza

7. Servicio de Medidas Físicas

8. Universidad de Zaragoza

9. Centro Universitario de la Defensa

10. “Petru Poni” Institute of Macromolecular Chemistry

11. Iasi

12. Romania

13. Institute of Chemistry

14. Academy of Sciences of Moldova

Abstract

The hepta-coordinated Co(bpy)_1.5(NO₃)₂ molecule exhibits a large crystal field induced anisotropy along its binary symmetry axis, as deduced from SQUID magnetometry, EPR, heat capacity measurements and ab initio simulations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2012/DT/C2DT31135F

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