Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry-Reference-Cited by-同舟云学术

Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry

Published:2022 Issue:8 Volume:51 Page:3280-3313
ISSN:0306-0012
Container-title:Chemical Society Reviews
language:en
Short-container-title:Chem. Soc. Rev.

Author:

Sutter Jean-Pascal¹^ORCID,Béreau Virginie¹²^ORCID,Jubault Valentin¹^ORCID,Bretosh Kateryna¹^ORCID,Pichon Céline¹^ORCID,Duhayon Carine¹^ORCID

Affiliation:

1. Laboratoire de Chimie de Coordination du CNRS (LCC-CNRS), Université de Toulouse, CNRS, Toulouse, France

2. Université de Toulouse, Institut Universitaire de Technologie Paul Sabatier-Département de Chimie, Av. Georges Pompidou, F-81104 Castres, France

Abstract

The magnetic anisotropy associated with a pentagonal bipyramidal coordination sphere is examined on the basis of experimental and theoretical investigations; effects of crystal field, structural distortion, and second coordination sphere are discussed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CS/D2CS00028H

Reference184 articles.

1. Magnetic anisotropy in two- to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

2. Large magnetic anisotropy in mononuclear metal complexes

3. Synthesis and characterization of novel pentagonal bipyramidal complexes of iron(II), cobalt(II), and zinc(II)

4. Seven-coordinate complexes of iron(II) with pentadentate macrocyclic ligands

5. X-Ray crystal structure of a planar, high-spin iron(II) complex of a pentadentate unsaturated macrocycle formed by reaction of 2,9-di(1-methylhydrazino)1,10-phenanthroline monohydrochloride with 2,6-diacetylpyridine

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