Geometry-dependent valence tautomerism, magnetism, and electrical conductivity in 1D iron–tetraoxolene chains-Reference-Cited by-同舟云学术

Geometry-dependent valence tautomerism, magnetism, and electrical conductivity in 1D iron–tetraoxolene chains

Published:2023 Issue:15 Volume:14 Page:4083-4090
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kamin Ashlyn A.¹^ORCID,Moseley Ian P.²^ORCID,Oh Jeewhan³,Brannan E. J.¹^ORCID,Gannon Paige M.¹,Kaminsky Werner¹,Zadrozny Joseph M.²^ORCID,Xiao Dianne J.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Washington, Seattle, Washington 98195, USA

2. Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA

3. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA

Abstract

Here we show how a simple change in the geometry of 1D iron–tetraoxolene chains dramatically alters the observed physical properties, including the presence of valence tautomerism, strong magnetic coupling, and electrical conductivity.

Funder

Arnold and Mabel Beckman Foundation

Research Corporation for Science Advancement

U.S. Department of Energy

University of Washington

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06392A