Gradual solid-state redox-isomerism in the lanthanide series-Reference-Cited by-同舟云学术

Gradual solid-state redox-isomerism in the lanthanide series

Published:2024 Issue:20 Volume:53 Page:8850-8856
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lukina Daria A.¹^ORCID,Skatova Alexandra A.¹,Rumyantcev Roman V.¹^ORCID,Demeshko Serhiy V.²,Meyer Franc²^ORCID,Fedushkin Igor L.¹^ORCID

Affiliation:

1. G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, Tropinina Str. 49, Nizhny Novgorod, 603137, Russian Federation

2. Institut für Anorganische Chemie, Georg-August-Universität Tammannstrasse 4, Göttingen 37077, Germany

Abstract

The dithiocarbamate derivative [(ArBIG-bian)Yb{SC(S)NMe2}(dme)] (2) exhibits a unique gradual solid-state redox-isomerism that involves a temperature-induced reversible electron transfer between the metal and the ligand.

Funder

Deutsche Forschungsgemeinschaft

Niedersächsische Ministerium für Wissenschaft und Kultur

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00484A

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