The secondary coordination sphere controlled reactivity of a ferric-superoxo heme: unexpected conversion to a ferric hydroperoxo intermediate by reaction with a high-spin ferrous heme-Reference-Cited by-同舟云学术

The secondary coordination sphere controlled reactivity of a ferric-superoxo heme: unexpected conversion to a ferric hydroperoxo intermediate by reaction with a high-spin ferrous heme

Published:2016 Issue:45 Volume:52 Page:7213-7216
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Nagaraju Perumandla¹²³⁴⁵,Ohta Takehiro⁵⁶⁷⁴⁸,Liu Jin-Gang⁹¹⁰¹¹¹²,Ogura Takashi⁸¹³¹⁴¹⁵¹⁶,Naruta Yoshinori¹²³⁴⁵

Affiliation:

1. Institute of Science and Technology Research

2. Chubu University

3. Kasugai

4. Japan

5. Institute for Materials Chemistry and Engineering

6. Kyushu University

7. Fukuoka 812-8581

8. Picobiology Institute

9. Department of Chemistry

10. East China University of Science and Technology

11. 200237 Shanghai

12. China

13. Graduate School of Life Science

14. University of Hyogo

15. RSC-UH LP Center

16. Hyogo 679-5148

Abstract

Incorporation of a proton mediator above the Fe porphyrin at a suitable position remarkably reduces the activation energy from the Fe-superoxide complex to the corresponding Fe-peroxide.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC02162J

Reference45 articles.

1. Heme-Containing Oxygenases

2. Mechanism of Oxidation Reactions Catalyzed by Cytochrome P450 Enzymes

3. Structure and Chemistry of Cytochrome P450

4. Differential Hydrogen Bonding in Human CYP17 Dictates Hydroxylation versus Lyase Chemistry

5. Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics

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