Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide–palladium catalysts-Reference-Cited by-同舟云学术

Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide–palladium catalysts

Published:2016 Issue:1 Volume:7 Page:737-744
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mitsushige Yusuke¹²³⁴⁵^ORCID,Carrow Brad P.⁶⁷⁸⁹,Ito Shingo¹²³⁴⁵^ORCID,Nozaki Kyoko¹²³⁴⁵

Affiliation:

1. Department of Chemistry and Biotechnology

2. Graduate School of Engineering

3. The University of Tokyo

4. Bunkyo-ku

5. Japan

6. Department of Chemistry

7. Princeton University

8. Princeton

9. USA

Abstract

A new series of palladium catalysts ligated by a chelating bisphosphine monoxide bearing diarylphosphino groups (aryl-BPMO) exhibits markedly higher reactivity for ethylene/methyl acrylate copolymerisation.

Funder

Core Research for Evolutional Science and Technology, Japan Science and Technology Agency

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC03361F

Reference56 articles.

1. Influence of Ziegler−Natta Catalyst Regioselectivity on Polypropylene Molecular Weight Distribution and Rheological and Crystallization Behavior

2. Crystallization Behavior and Mechanical Properties of Regiodefective, Highly Stereoregular Isotactic Polypropylene: Effect of Regiodefects versus Stereodefects and Influence of the Molecular Mass