Advance on nickel‐ and <scp>palladium‐catalyzed</scp> insertion copolymerization of ethylene and acrylate monomers-Reference-Cited by-同舟云学术

Advance on nickel‐ and palladium‐catalyzed insertion copolymerization of ethylene and acrylate monomers

Published:2023-08-08 Issue:23 Volume:61 Page:2987-3021
ISSN:2642-4150
Container-title:Journal of Polymer Science
language:en
Short-container-title:Journal of Polymer Science

Author:

Zheng Handou¹,Qiu Zonglin¹,Li Donghui¹,Pei Lixia²,Gao Haiyang¹^ORCID

Affiliation:

1. School of Materials Science and Engineering, PCFM Lab, GD HPPC Lab Sun Yat‐sen University Guangzhou China

2. School of Chemistry and Chemical Engineering South China University of Technology Guangzhou China

Abstract

AbstractNickel‐ and palladium‐catalyzed insertion copolymerization of ethylene and acrylate comonomers for synthesis of ethylene‐acrylates copolymers have attracted much academic and industrial interests and remained highly challenging. This review provides an overview of the developments in nickel‐ and palladium‐catalyzed insertion copolymerization of ethylene and acrylate comonomers. Mechanistic interpretation of metal‐catalyzed insertion copolymerization of ethylene and acrylate comonomers is described. Late transition metal catalysts are divided to nickel‐based and palladium‐based catalysts with different chelate ligands. The effects of catalyst structure on copolymerization performance and copolymer microstructure are comprehensively discussed. This review aims to promote the design and development of nickel and palladium catalysts for ethylene/acrylate copolymerizations and synthesis of ethylene‐acrylates copolymers.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

PetroChina

Publisher

Wiley

Subject

Materials Chemistry,Polymers and Plastics,Physical and Theoretical Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/pol.20230389

Reference165 articles.

1. Coordination−Insertion Copolymerization of Fundamental Polar Monomers

2. Material Properties of Functional Polyethylenes from Transition-Metal-Catalyzed Ethylene–Polar Monomer Copolymerization

3. Coordination Copolymerization of Polar Vinyl Monomers H2CCHX

4. Influence of colemanite on the fire retardancy of ethylene-vinyl acetate and ethylene-methyl acrylate copolymers

5. Copolymerization of Ethylene and Methyl Acrylate by Pyridylimino Ni(II) Catalysts Affording Hyperbranched Poly(ethylene-co-methyl acrylate)s with Tunable Structures of the Ester Groups