Hydroxy-assisted regio- and stereoselective synthesis of functionalized alkenes via phosphine-catalyzed β′-umpolung addition of o-hydroxy aromatic aldimines to allenoates-Reference-Cited by-同舟云学术

Hydroxy-assisted regio- and stereoselective synthesis of functionalized alkenes via phosphine-catalyzed β′-umpolung addition of o-hydroxy aromatic aldimines to allenoates

Published:2018 Issue:15 Volume:5 Page:2375-2378
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Cheng Kunpeng¹²³⁴⁵,Bao Yishu¹²³⁴⁵,Wang Jiahua¹²³⁴⁵,Dai Zonghao¹²³⁴⁵,Lu Jinrong¹²³⁴⁵,Zhou Qingfa¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Natural Medicines

2. Department of Organic Chemistry

3. China Pharmaceutical University

4. Nanjing

5. P. R. China

Abstract

An unprecedented β′-umpolung addition of o-hydroxy aromatic aldimines with allenoates has been developed under the catalysis of phosphine.

Funder

National Natural Science Foundation of China

Government of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00460A

Reference41 articles.

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2. Nucleophilic Phosphine Organocatalysis

3. Multifunctional Chiral Phosphine Organocatalysts in Catalytic Asymmetric Morita−Baylis−Hillman and Related Reactions

4. Development of asymmetric phosphine-promoted annulations of allenes with electron-deficient olefins and imines

5. Phosphine catalysis of allenes with electrophiles

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