Direct amination of poly(<i>p</i>-phenylene oxide) to substituted anilines over bimetallic Pd

Direct amination of poly(p-phenylene oxide) to substituted anilines over bimetallic Pd–Ru catalysts

Published:2024 Issue:7 Volume:26 Page:3949-3957
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Nguyen Phuc T. T.¹²^ORCID,Gözaydın Gökalp¹,Ma Jieran¹,Yao Bingqing³,He Qian³^ORCID,Yan Ning¹²^ORCID

Affiliation:

1. Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585, Singapore

2. Joint School of National University of Singapore and Tianjin University, Fuzhou 350207, Fujian, China

3. Department of Materials Science and Engineering, National University of Singapore, Singapore 117575, Singapore

Abstract

We demonstrate a novel route for the upcycling of poly(phenylene oxide) (PPO) into dimethylanilines using a bimetallic Pd7Ru3/CNT catalyst. This represents the first successful transformation of PPO into nitrogen-containing compounds.

Funder

National Research Foundation Singapore

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D3GC03757F

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