A sacrificial separator facilitating in situ creation of a durable CEI layer and tailoring lithium dendrites for practical lithium metal batteries

Author:

Park Sung Joon1,Choi Yun Jeong2,Cheon Jaemun3,Kim Hyungjun3,Lee Jong-Won4ORCID,Yim Taeeun3,Kim Ki Jae15ORCID

Affiliation:

1. Department of Energy Science, Sungkyunkwan University, Suwon, Gyeonggi-do 16419, Republic of Korea

2. Department of Energy Engineering, Konkuk University, Neungdong-ro 120, Gwangjin-gu, Seoul 05029, Republic of Korea

3. Department of Chemistry, Incheon National University, 119 Academy-ro, Yeonsu-gu, Incheon 22012, Republic of Korea

4. Division of Materials Science and Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea

5. SKKU Institute of Energy Science and Technology (SIEST), Sungkyunkwan University, Suwon 16419, Republic of Korea

Abstract

The TBB–PE separator can form a robust and uniform boron-rich CEI (cathode electrolyte interphase) layer on the cathode surface via electrochemical oxidation as well as inhibit the growth of lithium dendrites by anion anchoring.

Funder

Korea Environmental Industry and Technology Institute

National Research Foundation of Korea

Ministry of Education

Ministry of Trade, Industry and Energy

Publisher

Royal Society of Chemistry (RSC)

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