Reticular chemistry guided precise construction of zirconium-pentacarboxylate frameworks with 5-connected Zr6 clusters

Author:

Peng Tianyou12,Han Chao-Qin1,Xia Hai-Lun1,Zhou Kang1,Zhang Jian1,Si Jincheng31,Wang Lei1,Miao Jiafeng1,Guo Fu-An1,Wang Hao1ORCID,Qu Lu-Lu3ORCID,Xu Guozhong2,Li Jing41ORCID,Liu Xiao-Yuan1ORCID

Affiliation:

1. Hoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Blvd, Nanshan District, Shenzhen, 518055, P. R. China

2. College of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, P. R. China

3. School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, 221116, P. R. China

4. Department of Chemistry and Chemical Biology, Rutgers University, 123 Bevier Road, Piscataway, New Jersey 08854, USA

Abstract

A zirconium-pentacarboxylate framework is constructed using a pentacarboxylic acid with 5-connected Zr6 clusters guided by reticular chemistry. One isoreticular MOF can be utilized for HClO detection with excellent sensitivity and selectivity.

Funder

National Natural Science Foundation of China

Basic and Applied Basic Research Foundation of Guangdong Province

Shenzhen Science and Technology Innovation Program

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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