High adsorption selectivity, capacity and rate of fructose using metal–organic frameworks with abundant zirconium open metal sites

Author:

He Hai-Long12,Liu Zhongqi12,Liu Fengqing3,Chen Jie12,Wang Pu12,Yi Xianfeng3,Zheng Anmin3ORCID,Wang Lei1452ORCID

Affiliation:

1. School of Engineering, Westlake University, Hangzhou, Zhejiang, 310024, China

2. Institute of Advanced Technology, Westlake Institute for Advanced Study, Hangzhou, Zhejiang, 310024, China

3. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, National Center for Magnetic Resonance in Wuhan, Wuhan Institute of Physics and Mathematics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan, Hubei, 430071, China

4. Zhejiang Key Laboratory of Low-Carbon Intelligent Synthetic Biology, Westlake University, Hangzhou, Zhejiang, 310030, China

5. Research Center for Industries of the Future, Westlake University, Hangzhou, Zhejiang, 310030, China

Abstract

MOF-808 with abundant zirconium sites enables high adsorption selectivity (17.8), high capacity (362 mg g−1), and rapid adsorption and separation (18.9 h−1) of fructose from glucose and fructose mixed solutions and has excellent cycling stability.

Funder

National Natural Science Foundation of China

Westlake University

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Reference54 articles.

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