Iron-catalyzed efficient intermolecular amination of C(sp3)–H bonds with bromamine-T as nitrene source-Reference-Cited by-同舟云学术

Iron-catalyzed efficient intermolecular amination of C(sp3)–H bonds with bromamine-T as nitrene source

Published:2014 Issue:48 Volume:4 Page:25287-25290
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Wang Haiyu¹²³⁴⁵,Li Yuxi¹²³⁴⁵,Wang Zhiming¹²³⁴⁵,Lou Jun¹²³⁴⁵,Xiao Yuling¹²³⁴⁵,Qiu Guofu¹²³⁴⁵,Hu Xianming¹²³⁴⁵,Altenbach Hans-Josef⁶⁷⁸,Liu Peng¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Virology

2. Ministry of Education Key Laboratory of Combinatorial Biosynthesis and Drug Discovery, Wuhan University

3. School of Pharmaceutical Sciences

4. Wuhan University

5. Wuhan, China

6. Bergische Universität Wuppertal

7. FB 9, Organische Chemie

8. 42097 Wuppertal, Germany

Abstract

[Fe(N4Py)(CH₃CN)](ClO₄)₂ can efficiently catalyze intermolecular nitrene insertion of sp³ C–H bonds with bromamine-T as the nitrene source, forming the desired tosylprotected amines with NaBr as the by-product.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA02240H

Reference67 articles.

1. A. Ricci , Amino Group Chemistry , Wiley-VCH , Weinheim , 2000

2. Allylic Amination

3. Metal-Initiated Amination of Alkenes and Alkynes

4. Synthesis of secondary amines

5. Enantioselective Catalytic Aziridinations and Asymmetric Nitrene Insertions into CH Bonds

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