Pressure-induced anomalies and structural instability in compressed β-Sb2O3

Author:

Zou Yongtao12345ORCID,Zhang Wei6785,Li Xuefei910115,Ma Maining1213145,Li Xing’ao615165,Wang Chun-Hai12345,He Bin12345,Wang Shanmin12345,Chen Zhiqiang1718192021,Zhao Yusheng12345,Li Baosheng1718192021

Affiliation:

1. Academy for Advanced Interdisciplinary Studies

2. and Department of Physics

3. Southern University of Science and Technology

4. Shenzhen

5. China

6. School of Science

7. Southwest University of Science and Technology

8. Mianyang

9. Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education

10. Jilin Normal University

11. Siping 136000

12. Key Laboratory of Computational Geodynamics of Chinese Academy of Sciences

13. University of Chinese Academy of Sciences

14. Beijing 100049

15. Nanjing University of Posts and Telecommunications

16. Nanjing 210046

17. Mineral Physics Institute

18. State University of New York

19. Stony Brook

20. N.Y. 11794

21. USA

Abstract

Here, we have discovered a new high-pressure phase of Sb2O3, and reported pressure-induced anomalies in orthorhombic β-Sb2O3 (valentinite) by the combination of synchrotron in situ X-ray diffraction and first-principles theoretical calculations up to 40.5 GPa.

Funder

Division of Earth Sciences

National Nuclear Security Administration

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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